Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 274, Issue -, Pages 207-214Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2019.03.027
Keywords
Biomass-based carbon; Electro catalysis; Hydrogen evolution reaction; Metal-free; Nitrogen-doped
Funding
- Jiangsu Province Key Laboratory of Biomass Energy and Materials [JSBEM-S-201906]
- National Natural Science Foundation of China [31530010, 21401168]
- Special Project of Guangdong Province to Introduce Innovation and Entrepreneurship Team [2016ZT06N467]
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Metal-free electrocatalysts for hydrogen evolution reaction (HER) are very important for efficient supply of sustainable and clean fuel. Herein, metal-free N-doped porous carbon fibers (NPCF) is reported by carbonization, activation and nitrogen-doping of natural cattails. The carbon fibers possess high specific surface area (765 m(2) g(-1)) and lots of micropores. Excellent catalytic performances of NPCF are illustrated for HER from electrolysis of water in acidic media. An onset overpotential of 70 mV with a low Tafel slope of 135 mV.dec(-1) was observed for NPCF electrode. The electrocatalytic properties of NPCF are much better than those of commercial graphite powder, carbon nanotubes and super-P. NPCF also shows promising electrochemical durability with only 3% recession of current density after 20 h continuous operations. The high catalytic activities of NPCF are attributed to the relatively high specific surface area, abundant micropores, strong electrical conductivity, the high stability of biomass-derived carbon matrix and suitable N content. The preparation and high activities for HER of NPCF offer a novel idea for the promising preparation of metal-free carbon materials derived from earth-abundant biomass for more efficient and cleaner bulk chemical production.
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