Journal
JOURNAL OF POWER SOURCES
Volume 424, Issue -, Pages 254-260Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2019.03.113
Keywords
Electrolyte additive; Disulfide bonds; Dithiothreitol; Lithium-sulfur batteries; shuttle effect
Funding
- Science & Technology Commission of Shanghai Municipality [08D22270500]
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One of the major issues limiting the practical application of lithium-sulfur (Li-S) batteries is that the sluggish redox kinetics of polysulfide intermediates exacerbate the unavoidable shuttle effect, which causes low sulfur utilization, rapid capacity fade, and anode corrosion. Herein, we firstly add a novel type of electrolyte additive, biological reagents dithiothreitol (DTI), into the traditional electrolyte of Li-S batteries to suppress the shuttle effect. DTT is able to be stabilized in original electrolyte system at room temperature and selectively slice the-S-S-bonds of polysulfides. The electrochemical studies reveal DTT significantly accelerate the reactions kinetic in cycle process and thus effectively inhibit the shuttling of polysulfides. As a result, the hierarchical porous carbon/S cathode using the electrolyte with 10 g L-1 DTT exhibits a high rate performance (570 mA h g(-1) improved from 317 mAh g(-1) at 3 C), a high initial discharge capacity (808 mAh g(-1) at 0.5 C), and a superior cyclic stability (a low capacity fading rate of 0.025% per cycle over 500 cycles at 2 C). This strategy provides a new direction for achieving high energy density Li-S batteries and thus facilitating their practical application from the point of improving the kinetic sluggishness by electrolyte additive.
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