Journal
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume 23, Issue 7-8, Pages 889-897Publisher
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1088424619500755
Keywords
porphyrin; synthesis; mechanochemistry; MnO2; porphyrinogen; sustainability
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Funding
- FCT (Fundacao para a Ciencia e a Tecnologia, I.P.) [UID/QUI/00313/2019]
- European Regional Development Fund (ERDF), through COMPETE 2020 - Operational Programme for Competitiveness and Internationalization (OPCI) [POCI-01-0145-FEDER-016387]
- FCT - Fundacao para a Ciencia e a Tecnologia I.P.
- FCT
- PhD program CATSUS [FCT-PD/BD/135531/2018]
- Fundação para a Ciência e a Tecnologia [UID/QUI/00313/2019] Funding Source: FCT
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Looking tor sustainable synthetic methodologies, mechanochemistry as a new tool for one-step and two-step approaches for the synthesis of meso-substituted porphyrins was explored. The best results were obtained in a two-step procedure, under liquid-assisted grinding in the oxidation step using 2-methyltetrahydrofuran, an environmentally acceptable solvent, and MnO2 as a heterogeneous oxidant. The sustainability was assessed using two sustainability metrics, E-factor and EcoScale, which allow comparison between procedures and methods.
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