Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 13, Pages 8771-8781Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b01033
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Funding
- IISER Kolkata
- SERB
- DST-SERB
- U.G.C.
- D.S.T.
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Visible-light-induced metal-free trifluoromethylation of activated, carbocyclic, and unactivated vinylcyclopropanes via a ring-opening reaction using the Langlois reagent (CF3SO2Na) is reported to synthesize allylic trifluoromethylated derivatives. Allylic trifluoromethylation was achieved by a photo-oxidative single electron transfer (SET) process at an ambient temperature and under metal free conditions and visible-light irradiation using pyrylium salt as a photoredox catalyst. The reported methodology has an operational simplicity, broad substrate scope, high functional group tolerance, and scalability.
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