Journal
JOURNAL OF NATURAL PRODUCTS
Volume 82, Issue 7, Pages 1908-1916Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jnatprod.9b00245
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Funding
- NSF of China [21602082, 21602081, 21702051]
- Open Research Fund of State Key Laboratory of Environmental Chemistry and Ecotoxicology [KF2016-01]
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The total synthesis of putative penasulfate A was effectively achieved by a convergent strategy with a longest linear sequence of 14 steps and overall yield of 8.6%. The highlights of our strategy involved an E-selective olefin cross-metathesis, Suzuki cross-coupling, and a copper(I)-catalyzed coupling reaction.
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