Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 845, Issue -, Pages 39-47Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2019.05.041
Keywords
Molybdenum disulfide; Carbon nanotubes; Hydrogen evolution reaction
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Funding
- Basic Science Research Program through the National Research Foundation of Korea [NRF-2016R1D1A3B04931018]
- U.S. Department of Energy at the University of Nebraska [DE-FG02-07ER15842]
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Molybdenum disulfide, supported by a carbon nanotube matrix fabricated through the hydrothermal method, is found to be an alternative catalyst for enhanced hydrogen evolution reactions. The improved performance of carbon nanotube and molybdenum disulfide (CNT-MoS2) composites is attributed to the synergic effects of CNT and MoS2 that provide a good conducting network as well as a large surface area, increasing catalytic activity for the hydrogen evolution reaction. The synthesized CNT-MoS2 composite provides a low overpotential (-0.14 V), much lower than MoS2 itself (-0.29 V), at a current density of 10 mA cm(-2). The CNT-MoS2 composite shows lower resistance (24 Omega) compared to the MoS2 precursor (1000 0) at a frequency of 3000 Hz, demonstrating an improved composite conductivity. The CNT-MoS2 composite also exhibits high stability and excellent durability.
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