Journal
INORGANIC CHEMISTRY
Volume 58, Issue 14, Pages 9469-9475Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b01332
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Funding
- NSFC [21701002, 21401004, 21571092]
- Natural Science Foundation of Anhui Province [1508085QB36]
- Open Foundation of Anhui Laboratory of Molecule-based Materials [fzj19005]
- National Creative Plan of Students [201810370443]
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Herein, a series of Fe-based catalysts have been designed and prepared by grinding a mixture of MIL-88d and melamine, and then the mixture was followed by pyrolysis. An unusual Fe/Fe3C-activated site is uniformly encapsulated in the N-doped carbon tubes obtained by pyrolysis of the film-like nanocrystals of MIL-88d. Experimental characterizations and theoretical calculations demonstrate that the surface N sites can effectively trap the nitrobenzene and aniline by their phenyl groups with the formation of three C-N bonds that made the catalyst exhibit excellent catalytic activity (turnover frequencies of <= 11268 h(-1) calculated on the basis of nitrobenzene) and chemoselectivity for the reduction of nitro derivatives under facile conditions.
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