Journal
INORGANIC CHEMISTRY
Volume 58, Issue 15, Pages 9749-9755Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b00745
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Funding
- National Natural Science Foundation of China [51432006, 21671082]
- Ministry of Science and Technology of China [2011DFG52970]
- Ministry of Education of China for the Changjiang Innovation Research Team [IRT13R24]
- Ministry of Education [B13025]
- State Administration of Foreign Experts Affairs for the 111 Project [B13025]
- Innovation Program of Shanghai Municipal Education Commission
- Fundamental Research Funds for the Central Universities [JUSRP51725B]
- Australian Research Council [DP170100411]
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A 3D heterothiometallic cluster-based metal-organic framework was constructed from the new oligomeric decanuclear heterothiometallic building clusters [W-2(mu(3)-S)(6)(mu(4)-S)(2)Cu-8](4+), tetra-dentate 3-abpt units (3-abpt = 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole), and CN- bridges. It possesses an unprecedented (3,11)-connected architecture, luminescence, and highly sensitive 2,4,6-trinitrophenol (TNP) sensing properties in both organic and aqueous media.
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