Journal
INORGANIC CHEMISTRY
Volume 58, Issue 15, Pages 9562-9566Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b01334
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Funding
- Spanish MINECO [CTQ2015-68370-P, MAT2017-86826-R]
- Advanced Light Source, a Department of Energy, Office of Science User Facility [DE-AC02-05CH11231]
- Russian Science Foundation [17-73-20369]
- Ministry of Science and Higher Education of the Russian Federation
- Russian Science Foundation [17-73-20369] Funding Source: Russian Science Foundation
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The slow magnetic relaxation of Co-II ions in the elusive intermediate geometry between the trigonal prism and antiprism has been studied on the new [Co2L3](4+) and [CoZnL3](4+) coordination helicates [L is a bis(pyrazolylpyridine) ligand]. Solution paramagnetic H-1 NMR and solid-state magnetization measurements unveil single-molecule-magnet behavior with small axial anisotropy, as predicted previously.
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