4.6 Article

Recovery of Critical Rare-Earth Elements Using ETS-10 Titanosilicate

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 58, Issue 25, Pages 11121-11126

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.9b02623

Keywords

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Funding

  1. Department of Chemical Engineering at the Pennsylvania State University
  2. Institute for Natural Gas Research (INGaR) at the Pennsylvania State University
  3. 3M Company (the 3M Non-Tenured Faculty Award)
  4. National Aeronautics and Space Administration (NASA) under PA Space Grant Consortium
  5. Penn State Department of Physics
  6. National Science Foundation, Penn State MRSEC RET (Research Experience for Teachers) Site [DMR-1460920, DMR-1420620]
  7. John J. and Jean M. Brennan Clean Energy Early Career Professorship
  8. U.S. National Science Foundation [DMR-1420620]

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The present work deals with the recovery of critical rare-earth elements (REEs) from acidic aqueous solutions. In doing so, we study the adsorption of these ions on ETS-10 titanosilicate. The experimental data are individually fitted with the Langmuir and Freundlich isotherms, and a high adsorption capacity for REEs is found. We further explore the competitive separation of Nd3+ from Ni2+ ions and Dy3+ from Nd3+ ions usually found in aqueous streams generated during the recycling of NiMH batteries and NdFeB permanent magnets, respectively, via adsorption using ETS-10.

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