Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 31, Issue 2, Pages -Publisher
WILEY
DOI: 10.1002/aoc.3566
Keywords
magnetite nanocatalyst; ZnCl2; quinolines; Friedlender
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Funding
- Research Council of Razi University
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A magnetic nanocatalyst of Fe3O4@SiO2/ZnCl2 was prepared by supporting ZnCl2 on silica-coated magnetic nanoparticles of Fe3O4. This recoverable catalyst was used for the synthesis of quinolines via Friedlader synthesis from 2-aminoaryl ketones and a-methylene ketones under solvent-free condition. The prepared catalyst was characterized by FT-IR, TEM, SEM, XRD, EDX, ICP-OES, VSM and BET. It was found that Fe3O4@SiO2/ZnCl2 showed higher catalytic activity than homogenous ZnCl2, and could be reused several times without significant loss of activity.
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