Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 30, Issue 11, Pages 905-910Publisher
WILEY-BLACKWELL
DOI: 10.1002/aoc.3519
Keywords
hydrosilylation; rhodium complex; silylated triarylphosphine ligands; beta-adduct selectivity
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Funding
- National Natural Science Foundation of China [21203049, 21303034]
- Fund of Zhejiang Province [LY14B030007]
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A series of silylated triarylphosphines was synthesized. Hydrosilylation reactions of styrene with triethoxysilane catalyzed by RhCl3/silylated triarylphosphine complexes were investigated. The complexes RhCl3/phenylbis(4-trimethylsilylphenyl)phosphine and RhCl3/tris(4-trimethylsilylphenyl)phosphine exhibited higher activity as well as greater beta-adduct selectivity, and no unsaturated product was obtained. The results suggest that the silyl moieties have a significant impact on the catalytic process. Copyright (C) 2016 John Wiley & Sons, Ltd.
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