Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2019, Issue 33, Pages 5732-5735Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201900900
Keywords
alpha-Ketoamides; beta-Ketonitriles; C-C bond cleavage; Amidation; Decyanation
Categories
Funding
- National Natural Science Foundation of China [21172120, 21472093]
- Tianjin Municipal Science and Technology Commission [14JCYBJC20600]
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AN oxidative decyanation-amidation of beta-ketonitriles and primary amines readily occurs using hydrogen peroxide sodium carbonate adduct (Na2CO3 center dot 1.5H(2)O(2)), K2CO3, and 1,4-dioxane. This reaction affords alpha-ketoamides under mild conditions without the need of a catalyst.
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