Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 30, Issue 9, Pages 767-771Publisher
WILEY
DOI: 10.1002/aoc.3504
Keywords
arylsulfonyl chlorides; Pd-catalyzed; Suzuki-Miyaura coupling; aryl trifluoroborates
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Funding
- Science and Technology Research and Development Programs of Hebei Province, Zhangjiakou City [1411070B, 1511075B, 1411058I-23]
- Major Project of Hebei North University [ZD201304]
- Hebei Provincial Education Department Youth Fund Projects [QN2015148, QN2015007]
- Health Department of Hebei Province Project [20160030]
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A Pd-catalyzed cross-coupling of aryl trifluoroborates with arylsulfonyl chlorides has been successfully achieved. This transformation is a new method for the Suzuki-Miyaura-type reaction of aryl trifluoroborates via the cleavage of C S bond, thus providing an alternative synthesis of biaryls. The reported cross-coupling reactions are tolerant to many common functional groups regardless of electron-donating or electron-withdrawing nature, making these transformations attractive alternatives to the traditional Suzuki-Miyaura coupling approaches. Copyright (c) 2016 John Wiley & Sons, Ltd.
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