Journal
COORDINATION CHEMISTRY REVIEWS
Volume 390, Issue -, Pages 50-75Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2019.03.012
Keywords
Metal-organic frameworks; Photocatalysts; Water splitting; Hydrogen production
Categories
Funding
- NSFC [21625103, 21571107, 21421001]
- 111 Project [B12015]
- National Programs of the Nano-Ket Project [2017YFA0206700]
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Owing to the structural controllability, pore modification and unique semiconductor property of metal-organic frameworks (MOFs), the investigation on MOFs as efficient photocatalysts for hydrogen production from water splitting under UV, visible or even NIR light irradiation have made great progress. In this review, we systematically summarized the recent advances of MOFs-based photocatalysts for hydrogen production from water, and divided them into three categories: MOFs, MOFs composites and MOFs-derived photocatalysts. The high hydrogen production efficiency and possible hydrogen production mechanism of MOFs-based photocatalysts were analyzed in detail. A brief perspective was given to achieve high effective and stable MOFs-based materials for photolysis of water, providing suggestions to explore new and efficient MOFs-based photocatalysts. (C) 2019 Elsevier B.V. All rights reserved.
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