Journal
COMPOSITES PART B-ENGINEERING
Volume 167, Issue -, Pages 690-699Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesb.2019.03.055
Keywords
Mesoporous shell; Hollow microspheres; Dielectric loss; Electromagnetic wave absorption
Funding
- National Natural Science Foundation of China [51407134, 51801001]
- China Postdoctoral Science Foundation [2016M590619, 2016M601878]
- Natural Science Foundation of Shandong Province [ZR2016EEQ28]
- Fundamental Research Funds for the Central Universities [3102018zy045]
- Natural Science Basic Research Plan in Shaanxi Province of China [2017JQ5116]
- Thousand Talents Plan
- Taishan Scholar's Advantageous and Distinctive Discipline Program of Shandong Province
- World-Class Discipline Program of Shandong Province
- World-Class University and Discipline
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Carbon hollow microspheres with a uniform mesoporous shell (PCHMs) were designed and fabricated using a template-assistant method followed by a pyrolysis-etching process. Through tuning the pyrolysis temperature, PCHMs with various pore size and shell thickness can be obtained. In particular, the PCHMs carbonized at 650 degrees C (PCHMs-650) are composed of a mesoporous shell (thickness: 52 nm) and an interior void of 153 nm, endowing the materials with large surface area of 925.9 m(2)/g. The unique core-shell structure generated by carbon shell and void core is critical for the attenuation capability of EM energy. The composites containing 20 wt% PCHMs-650 exhibit favorable microwave absorbing performance with the minimum reflection loss (RLmin) of -39.4 dB at ]3.6 mm. The broadest effective absorption bandwidth (EAB) can extend to 5.28 GHz (9.68-14.96 GHz) at only 2.6 mm. It is believed that PCHMs can be used as a promising absorber with light-weight, impressive bandwidth and strong absorption efficiency.
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