4.6 Article

Sessile droplets shape response to complex body forces

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.colsurfa.2019.03.096

Keywords

Forced wetting; Tangential force; Droplet shape; Contact angle; Young-Laplace equation

Funding

  1. Marie-Curie ITS Complex wetting Phenomena, CoWet (FP7-PEOPLE-2013-ITN) [607861]
  2. MAP Project Enhanced Condensers in Microgravity, ENCOM-3 (European Space Agency) [4200020276]
  3. COST Action [MP1305]

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The majority of studies on forced wetting of sessile droplets refers to application of a steadily increasing normal or tangential force or to a specific combination of these forces arising from tilting the substrate. The above constitute well-defined test conditions but are not representative of what is encountered in most industrial applications. To approach realistic industrial conditions and so also expand existing wetting theories, an evaluation of droplet shape deformation under the influence of a complicated evolution of body forces, is performed herein. To this aim, two sets of experiments are carried out in Kerberos device creating force fields by combination of gravitational and centrifugal forces: i) by oscillations of the tilting angle at constant rotation speed and ii) by alternating small step-increases of the rotation speed and the tilting angle, one after the other, so as to trail the symmetric side profile (SSP) curve of a droplet. The latter is done in three or six steps following two different paths: increasing first either the rotation speed or the tilting angle. The aim of the experiments is, on one hand, to explore droplet deformation under cycles of increasing/decreasing tangential forces and, on the other hand, to analyze the effect of residual tangential forces on droplet shape. Several features related to the droplet shape evolution are investigated such as contact angles, side and top contour profiles and droplet 3-dimensional shape. The resulting droplet profiles are analyzed using numerical solutions of the Young-Laplace equation. It is found that the 3-dimensional Young Laplace equation can describe very accurately the experimental profiles.

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