Efficient natural pyrrhotite activating persulfate for the degradation of O-isopropyl-N-ethyl thionocarbamate: Iron recycle mechanism and degradation pathway

Natural pyrrhotite (NP) shows promising future in activating persulfate (PS) due to its easy availability at a low cost and easy separation. This study discussed the degradation of O-isopropyl-N-ethyl thionocarbamate (IPETC) in NP/PS system. NP-PS system showed the best IPETC mineralization at the initial pH of 6.0 (62.84%). The kinetics study suggested that the IPETC degradation followed the pseudo-firstorder equation in the NP-PS system. NP-PS system worked better in bottled water (96.46%) and tap water (85.14%) than river water (31.28%). Combined with Fourier transform-infrared spectroscopy, gas chromatography-mass spectrometry and computational calculation, the degradation products, including acetone, formic acid isopropyl ester and ethylamine, were identified and the degradation pathway of IPETC in NP-PS system was proposed. The S, O and N atoms in IPETC are easier to be attacked by. SO4 Ethylamine and reduced S ions coordinately worked to recycle Fe2+ in NP/PS/IPETC system. (C) 2019 Elsevier Ltd. All rights reserved.