Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 14, Issue 20, Pages 3597-3602Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201900458
Keywords
dynamic response; interpenetration; metal-organic framework; nitroaromatic explosives detector
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Funding
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- National Natural Science Foundation of China [21671189, 21731006]
- Key Research Program of Frontier Sciences, CAS [QYZDY-SSW-SLH025]
- Natural Science Foundation of Fujian Province [2017J01029]
- Youth Innovation Promotion Asso-ciation CAS
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A flexible two-fold interpenetrated indium metal-organic framework InOF-23, featuring one-dimensional micro-sized channels decorated by exposed N groups, was successfully synthesized. Interestingly, InOF-23 displays unique dynamic responses to different gases (N-2, Ar, and CO2) at low and room temperatures, which indicates that it can be a good candidate for gas adsorption and separation. Furthermore, the high efficiency detection for p-nitroaniline (pNA) makes InOF-23 a potential chemosensor for nitroaromatic explosives.
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