Journal
CHEMICAL REVIEWS
Volume 119, Issue 14, Pages 8846-8953Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.9b00033
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Funding
- French National Agency [ANR-16-CE07-0019-01, ANR-15-CE29-0012-03]
- University of Gabes
- Campus France
- Agence Nationale de la Recherche (ANR) [ANR-15-CE29-0012] Funding Source: Agence Nationale de la Recherche (ANR)
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In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-group elements. Enantioenriched helicenic derivatives containing main group elements B, Si, N, and P, either incorporated within the helical backbone or grafted to it, will be thoroughly presented. We will describe their synthesis, resolution, and asymmetric synthesis, their structural features, electronic and chiroptical properties, and emission, together with other photochemical properties and applications.
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