Journal
CHEMICAL PHYSICS LETTERS
Volume 725, Issue -, Pages 14-17Publisher
ELSEVIER
DOI: 10.1016/j.cplett.2019.03.061
Keywords
Pure rotational transitions; cis-OSOO; Molecular structure; Discharge plasma
Funding
- Ministry of Science and Technology of Taiwan [MOST 104-2113-M-009-202]
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Pure rotational transitions of cis-OSOO are identified in a discharge plasma of a SO2 and O-2 gaseous mixture by Fourier-transform microwave (FTMW) and FTMW-MW double-resonance spectroscopy. Both a- and b-type transitions are observed for this molecule, and the rotational and centrifugal distortion constants are precisely determined from the observed line positions. The inertial defect calculated from the determined rotational constants indicates that the cis-OSOO molecule has a planar equilibrium geometry in the ground vibronic state.
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