Journal
CARBOHYDRATE POLYMERS
Volume 214, Issue -, Pages 53-61Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2019.02.094
Keywords
Coffee residue; Arabinogalactans; Galactomannans; Polysaccharides; Methylation analysis; Response surface methodology
Categories
Funding
- project PulManCar - FEDER through COMPETE2020 - Programa Operacional Competitividade e Internacionalizacao (POCI) [POCI-01-0145-FEDER-029560]
- FCT/MCTES [UID/AMB/50017 - POCI-01-0145-FEDER-007638]
- University of Aveiro [FCT UID/QUI/00062/2019]
- FCT/MCT - FEDER [FCT UID/QUI/00062/2019]
- FEDER, within the PT2020 Partnership Agreement
- Compete 2020
- CICECO-Aveiro Institute of Materials [POCI-01-0145-FEDER-007679]
- FCT - FCT/MEC [UID/CTM/50011/2013]
- FEDER under the PT2020 Partnership Agreement
- FCT [SFRH/BPD/107881/2015, SFRH/BPD/104265/2014, SFRH/BD/104855/2014]
- FCT
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This work studies the microwave-assisted extraction conditions for recovery of polysaccharides from spent coffee grounds, including their effect on arabinogalactans and galactomannans polymerization and branching structural features. Temperature (140, 170, and 200 degrees C) has the most significant impact on total extracted mass (eta(total) (soluble) (solids)) and sugars yield (eta(sugars)), arabinogalactans (eta(AG)) and galactomannans (eta(GM)), and polysaccharide mass ratio (eta(AG)/eta(GM)). Time (2, 5, and 10 min) and alkali (diluted 0.1 M NaOH) treatments have less influence. Alkali treatment and shorter time (2 min) provided a protective effect against polysaccharides degradation. At 170 degrees C, the yield of arabinogalactans was found to be significantly higher than that of galactomannans (eta(AG)/eta(GM) > 1). Increasing temperature to 200 degrees C leads to decrease the polymerization of polysaccharides, promoting the formation of debranched polysaccharides and oligosaccharides. This study shows that the optimum conditions for polysaccharides extraction cannot be selected only by mass yield but need to be defined according to the desired structural features for the specific applications.
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