Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 15, Issue -, Pages 1523-1533Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.15.155
Keywords
ditihiocarbamate; elemental sulfur; multicomponent reaction; one-pot; thiocarbamate
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Funding
- Hungarian Science Foundation OTKA [PD124598]
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A new multicomponent reaction has been developed between isocyanides, sulfur and alcohols or thiols under mild reaction conditions to afford O-thiocarbamates and dithiocarbamates in moderate to good yields. The one-pot reaction cascade involves the formation of an isothiocyanate intermediate, thus a catalyst-free synthesis of isothiocyanates, as valuable building blocks from isocyanides and sulfur is proposed, as well. The synthetic procedure suits the demand of a modern organic chemist, as it tolerates a wide range of functional groups, it is atom economic and easily scalable.
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