Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 246, Issue -, Pages 356-366Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2019.01.064
Keywords
Soot oxidation; Macroporous structure; Ag-loaded CeO2; Surface oxygen vacancies; Active oxygen species
Funding
- National Research Foundation of Korea (NRF) - Korea government (MSIP) [NRF-2016R1A5A1009592]
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A series of CeO2-based catalysts were investigated for soot oxidation with O-2. The macroporous CeO2 catalyst (MCeO2) showed higher soot oxidation activity than mesoporous CeO2 due to the enhanced contact between catalyst and soot caused by the large pore size of M-CeO2. Moreover, various amounts of Ag (2-20 wt.%) were introduced to M-CeO2 to increase the activity, and the Ag-incorporated macroporous CeO2 catalysts (Ag(x)_M-CeO2) were characterized. Raman spectra showed that the ratio of active oxygen species (O-x(n-)) were different according to amount of Ag. The ratio of highly reactive superoxide (O-2(-)) was largest for the Ag(5)_M-CeO2 catalyst, and then it was decreased as the Ag amount increased further. In addition, XPS analysis showed that the difference in O-x(n-) generation could be attributed to diverse surface oxygen vacancies in the catalysts. Hence, the amount of loaded Ag affected the surface oxygen vacancies of Ag(x)_M-CeO2 and consequently the ratio of O-x(n-) was different according to the surface oxygen vacancies of the catalysts. Ag(5)M-CeO2 with the appropriate surface oxygen vacancies induced the promotion of O-2(-) generation, resulting in the best soot oxidation activity. It was concluded that the amount of Ag on CeO2 has a great influence on the catalytic soot oxidation activity, and proper surface oxygen vacancies facilitated O-2(-) generation, whereas excessive surface oxygen vacancies hindered the formation of highly reactive O-x(n-).
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