Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 40, Pages 14110-14114Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201906913
Keywords
alkylation; carbon dioxide; C-H functionalization; phosphine ligands; rhodium
Categories
Funding
- CNRS, UR1
- China Scholarship Council (CSC) [201706780007]
Ask authors/readers for more resources
We report the C-H alkylation of biarylphosphines at the ortho ' position(s) with alkenes by using rhodium(I) catalysis, which provides straightforward access to a large library of multifunctionalized phosphines. Some of these modified ligands outperformed commercially available phosphines in the Pd-catalyzed carboxylation of aryl bromides with carbon dioxide in the presence of a photoredox catalyst.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available