Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 34, Pages 11791-11795Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201906416
Keywords
black phosphorus; phase junction; photocatalysis; water splitting; Z-scheme
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Funding
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB17000000]
- Natural Science Foundation of China [21773275, 21633015, 11721404]
- Ministry of Science and Technology [2018YFA0208701]
- K.C. Wong Education Foundation
- CAS-Croucher Funding Scheme for Joint Laboratories
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Black phosphorus (BP) has recently drawn attention in photocatalysis for its optical properties. However, limited by the rapid recombination of photogenerated carriers, the use of BP for photocatalytic water splitting still remains a huge challenge. Herein, we prepare a black/red phosphorus (BP/RP) hetero-phase junction photocatalyst by a wet-chemistry method to promote the interfacial charge separation and thus achieve Z-scheme photocatalytic water splitting without using sacrificial agents. The Z-scheme mechanism was confirmed by time-resolved transient absorption spectroscopy. This work provides a novel insight into the interface design of hetero-phase junction with atomic precision.
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