4.8 Article

Metal-Organic Framework-Activated Carbon Composite Materials for the Removal of Ammonia from Contaminated Airstreams

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 34, Pages 11747-11751

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201905779

Keywords

activated carbons; gas adsorption; metal-organic frameworks; porous materials; water stability

Funding

  1. EPSRC industrial CASE award [EP/N50936X/1]
  2. Fondo per il finanziamento delle attivita base di ricerca [PJ-RIC-FFABR_2017]

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Metal-organic frameworks (MOFs) are a class of porous materials that show promise in the removal of toxic industrial chemicals (TICs) from contaminated airstreams, though their development for this application has so far been hindered by issues of water stability and the wide availability and low cost of traditionally used activated carbons. Here a series of three MOF-activated carbon composite materials with different MOF to carbon ratios are prepared by growing STAM-17-OEt crystals inside the commercially available BPL activated carbon. The composite materials display excellent water stability and increased uptake of ammonia gas when compared to unimpregnated carbon. Such properties make these composites very promising in the fields of air purification and personal protective equipment.

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