Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 32, Pages 10956-10960Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201904861
Keywords
alkenes; arylboration; boron; cross coupling; nickel
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Funding
- Indiana University
- National Institutes of Health [R01GM114443, R35GM131755]
- Vice Provost for Research through the Research Equipment Fund
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A method for the construction of boron-substituted quaternary carbons or diarylquaternary carbons by arylboration of highly substituted alkenylarenes is presented. A wide range of alkenes and arylbromides can participate in this reaction thus allowing for a diverse assortment of products to be prepared. In addition, a solvent dependent regiodivergent arylboration of 1,2-disubstituted alkenylarenes is presented, thus greatly increasing the scope of products that can be accessed.
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