Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 58, Issue 32, Pages 11054-11057Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201906148
Keywords
arylacetaldehydes; arylation; arylboronic acids; iridium catalysis; vinylene carbonate
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The one-step synthesis of arylacetaldehydes by carbon-carbon bond formation between formylmethyl and aryl groups has been realized by the reaction of vinylene carbonate with arylboronic acids in the presence of an iridium/bisphosphine catalyst and a catalytic amount of tetrahydroxydiboron.
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