Self-assembly of CPO-27-Mg/TiO2 nanocomposite with enhanced performance for photocatalytic CO2 reduction

CPO-27-Mg (also referred to as Mg-2(DOBDC), DOBDC=2,5-dioxido-1,4-benzenedicarboxylate), a Mg2+ based metal-organic framework which shows the highest CO2 uptake among the already reported MOF materials, was chosen to combine with TiO2 to form CPO-27-Mg/TiO2 nanocomposite via a hydrothermal self-assembly method. The as-obtained CPO-27-Mg/TiO2 nanocomposite is composed of TiO2 nanospheres on the spindle-shaped CPO-27-Mg microcrystal. Intimate contact between CPO-27-Mg and TiO2 nanospheres exists due to the coordination between the carboxylate groups in DOBDC and TO4+ in TiO2. The as-obtained CPO-27-Mg/TiO2 nanocomposite exhibited enhanced performance for the photocatalytic CO2 reduction to form CO and CH4 due to its high adsorption capacity toward CO2 and the existence of open alkaline metal sites in CPO-27-Mg. By incorporating MOFs with open alkaline metal center into TiO2, the reduction of H2O to H-2, a competitive reaction to photocatalytic CO2 reduction, was totally inhibited. This study highlights the promising prospect of incorporating MOFs with open alkaline metal sites into semiconductors for artificial CO2 photo-conversion. (C) 2015 Elsevier B.V. All rights reserved.