Identification of Cu surface active sites for a complete nitrate-to-nitrite conversion with nanostructured catalysts

Nitrate reduction on Pt nanostructured films, Pt-NSF, with an extended surface area (roughness factor of ca. 30), and close to 50% of (100) surface sites modified by Cu adatoms through underpotential deposition (Cu-upd/Pt-NSF), has been studied by means of linear sweep voltammetry (LSV), electrolysis at constant potential, and chemical analysis of the formed products. According to the LSV curves, the adsorption and reduction of nitrates occur preferentially at Cu(100) surface sites and at a potential positive (+0.15 V) of the hydrogen reversible potential. In these conditions, the nitrate-to-nitrite conversion is achieved on the Cu(100) sites, with a faradic efficiency in excess of 95%, and a conversion selectivity of 98%. (C) 2016 Elsevier B.V. All rights reserved.