Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 361, Issue 21, Pages 4998-5004Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201900766
Keywords
PIDA; Selenylations; Indoline; C-H functionalization; Radical reactions
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Funding
- Sichuan Science and Technology Program [2018JY0247, 2019YJ0282]
- National Natural Science Foundation of China [21502010]
- Key Laboratory of Medicinal and Edible Plants Resources Development of Sichuan Education Department [10Y201708]
- youth foundation of Chengdu University [2018XZB01]
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An efficient PIDA (phenyliodine(III) diacetate)-promoted positional selective C-H selenylations of indolines with diaryl diselenides has been developed. This transformation conducted under mild reaction conditions with a broad functional group tolerance, thus providing an efficient protocol to selenylated indolines. Preliminary mechanistic studies indicated a SET pathway was likely involved in this selenylation reaction.
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