Journal
ACS NANO
Volume 13, Issue 8, Pages 9161-9170Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.9b03492
Keywords
ordered graphene solid; capacitive cathode; sodium-ion capacitor; ultrahigh volumetric capacity; excellent rate capability
Categories
Funding
- National Key R&D Program of China [2 0 1 6YFA0 2 0 0 2 0 0, 2017YFB1104300]
- NSFC [21674056, 51433005, 51673026]
- Beijing Municipal Science and Technology Commission [Z161100002116022]
- NSFC-MAECI [51861135202]
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As an emerging type of electrochemical energy storage devices, sodium -ion capacitors (SICs) are potentially capable of high energy density and high power density, as well as low cost and long lifespan. Unfortunately, the lack of high-performance capacitive cathodes that can fully couple with the well-developed battery-type anodes severely restricts the further development of SICs. Here, we develop a compact yet highly ordered graphene solid (HOGS), which combines the merits of high density and high porosity and, more attractively, possesses a highly ordered lamellar texture with low pore tortuosity. As the capacitive cathode of SICs, HOGS delivers a record-high volumetric capacity (303 F cm(-3) or 219 mA h cm(-3) at 0.05 A g(-1)), a superior rate capability (185 F cm(-3) or 139 mA h cm(-3) even at 10 A g(-1)), and an outstanding cycling stability (over 80% after 10 000 cycles). The material design and construction strategies reported here can be easily extended to other metal -ion -based energy storage technologies, exhibiting universal potentials in compact electrochemical energy storage systems.
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