Journal
PROCESSES
Volume 7, Issue 6, Pages -Publisher
MDPI
DOI: 10.3390/pr7060319
Keywords
photocatalysis; TiO2 nanotubes; emerging contaminants; paracetamol; pH
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Funding
- Universidad del Valle [1004]
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Pharmaceuticals are considered among the group of emerging contaminants. Paracetamol is a moderate painkiller, which has been detected in ground and surface water. Photodegradation of paracetamol at a wavelength of radiation of 254 nm with TiO2 nanotubes was studied by UV-spectroscopy, HPLC and measurement of the potential zeta in dependence of the solution pH. The efficiency of the photodegradation of paracetamol (20 mg L-1) was 99% after 100 min exposure. Application of the Langmuir-Hinshelwood equation allowed the evaluation of the rate constant. Non-organic by-products were detected under the conditions of the chromatographic analysis. The photoreaction was faster at pH 6.5, a value at which adsorption was favored, leading to higher efficiency.
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