Journal
CHEMISTRYSELECT
Volume 4, Issue 11, Pages 3002-3005Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201803591
Keywords
Asymmetric synthesis; Crimmin's non-Evans syn aldol reaction; Enzymatic Desymmetrization; Macrolides; Ring closing metathesis
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Funding
- UGC, New Delhi
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A convergent and highly stereoselctive synthesis of macrolide framework of aldgamycin - M is described. The salient features of the synthesis are the utilization of enzymatic desymmetrization, Crimmin's non-Evans syn aldol reaction, Wittig olefination, Yamaguchi esterification and Ring closing metathesis reaction (RCM).
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