Journal
2D MATERIALS
Volume 6, Issue 3, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/2053-1583/ab1a4c
Keywords
cylindrite; sulfosalt; van der Waals superlattice; magnetic interactions; mechanical exfoliation; liquid-phase exfoliation
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Funding
- China Scholarship Council [201506120102]
- European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (ERC-StG 2017 project 2D-TOPSENSE) [755655]
- EU [785219]
- Netherlands Organisation for Scientific Research (NWO) through the research program Rubicon [680-50-1515]
- European Commission under the Marie Sklodowska-Curie programme [MSCA-IF 746579]
- Comunidad de Madrid Atraccion del Talento Programme [2017-T1/IND-5562]
- European Research Council [ERC-StG-MINT 307609]
- Ministerio de Economia y Competitividad [CTQ2014-60541-P, CTQ2017-86060-P]
- Comunidad de Madrid (MAD2D-CM program) [S2013/MIT-3007]
- 'Severo Ochoa' Programme for Centres of Excellence in RD (MINECO) [SEV-2016-0686]
- Juan de la Cierva program (MINECO-Spain) [FJCI-2015-25427]
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We report the isolation of thin flakes of cylindrite, a naturally occurring van der Waals superlattice, by means of mechanical and liquid phase exfoliation. We find that this material is a heavily doped p-type semiconductor with a narrow gap (<0.85 eV) with intrinsic magnetic interactions that are preserved even in the exfoliated nanosheets. Due to its environmental stability and high electrical conductivity, cylindrite can be an interesting alternative to the existing 2D magnetic materials.
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