Journal
NANOMATERIALS
Volume 9, Issue 5, Pages -Publisher
MDPI
DOI: 10.3390/nano9050668
Keywords
sulfonated polymer composites; organic membrane; inorganic membrane; organic-inorganic hybrid membrane; fuel cell
Categories
Funding
- National Natural Science Foundation of China (NSFC) [U1601211, 51573215, 21506260]
- Guangdong Province Sci Tech Bureau [2017B090901003, 2016B010114004]
- Natural Science Foundation of Guangdong Province [2016A030313354]
- Guangzhou Scientific and Technological Planning Project [201607010042, 201707010424, 201804020025]
- Fundamental Research Funds for the Central Universities [171gjc37]
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This paper focuses on a literature analysis and review of sulfonated polymer (s-Poly) composites, sulfonated organic, inorganic, and organic-inorganic hybrid membranes for polymer electrolyte membrane fuel cell (PEM) systems, particularly for methanol fuel cell applications. In this review, we focused mainly on the detailed analysis of the distinct segment of s-Poly composites/organic-inorganic hybrid membranes, the relationship between composite/organic- inorganic materials, structure, and performance. The ion exchange membrane, their size distribution and interfacial adhesion between the s-Poly composites, nanofillers, and functionalized nanofillers are also discussed. The paper emphasizes the enhancement of the s-Poly composites/organic-inorganic hybrid membrane properties such as low electronic conductivity, high proton conductivity, high mechanical properties, thermal stability, and water uptake are evaluated and compared with commercially available Nafion((R)) membrane.
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