Journal
JOURNAL OF ENERGY CHEMISTRY
Volume 41, Issue -, Pages 216-224Publisher
ELSEVIER
DOI: 10.1016/j.jechem.2019.05.016
Keywords
Hydrogen carriers; Formate salts; Bicarbonate salts; Thermodynamics
Funding
- Hydrogen Materials -Advanced Research Consortium (HyMARC) under the U.S. Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office
- National Research Foundation (NRF) of Korea - Ministry of Science and ICT [2015M1A2A2074688]
- KIST institutional program - Korea Institute of Science and Technology [2E29610]
- National Research Foundation of Korea [2E29610, 2015M1A2A2074688] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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In this perspective article, the synthesis and thermodynamic properties of aqueous solutions of formate salts (FS, HCO2-) are described in relationship to the concept of H-2 carriers. The physiochemical properties of solid FS, aqueous formate solutions, and aqueous bicarbonate solutions set the limitations for storage capacity, deliverable capacity, and usable H-2 capacity of these H-2 carriers, respectively. These parameters will help in the design of systems that use H-2 carriers for storage and transport of H-2 for fuel cell power applications. FS, as well as admixtures with formic acid (FA, H2CO2), have potential to address the goals outlined in the U.S. Department of Energy's H2@scale initiative to store in chemical bonds a significant quantity of energy (hundreds of megawatts) obtained from large scale renewable resources. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
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