Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 8, Issue 6, Pages 802-813Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201900102
Keywords
glycosylation; diastereoselectivity; oligosaccharides; glycosides; carbohydrates
Categories
Funding
- National Science Foundation [NSF CHE-1566233]
- National Institutes of Health [R01-GM115779, U01-GM120414]
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Because of their pivotal biological functions, attention to sugars and glycobiology has grown rapidly in recent decades, leading to increased demand for homogeneous oligosaccharides. The stereoselective preparation of oligosaccharides by chemical means remains challenging and continues to be a vivid research area for organic chemists. In the past decade, new approaches and reinvestigated traditional methods have transformed the field. These developments include novel catalyses, various types of glycosylation modulators and the use of photochemical energy to facilitate glycosylation. This Minireview presents a brief overview of the latest trends in chemical glycosylation, with emphasis on the stereoselective synthetic protocols developed in the past decade.
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