Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 7, Issue 9, Pages 8893-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.9b00904
Keywords
Green chemistry; Heterogeneous catalysis; Covalent triazine framework; Transfer hydrogenation; Ru catalysis
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Funding
- C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT AMP
- Future Planning [2018M3D3A1A01018006]
- National Research Foundation of Korea [2018M3D3A1A01018006] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A heterogeneous Ru catalyst, [(bpy-CTF)-RuCl3], which is synthesized by the coordinative immobilization of RuCl3 center dot xH(2)O on a bipyridyl-functionalized covalent triazine framework (bpy-CTF), is an efficient catalyst for the transfer hydrogenation (TH) of various carbonyl compounds into alcohols in water using HCOONa as a benign reducing agent. The as-prepared heterogeneous catalyst exhibits a very high turnover number (similar to 990) and an initial turnover frequency (44.8 h(-1)) as well as excellent recyclability, which makes it a greener catalyst for industrial applications in TH.
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