Journal
ACS CATALYSIS
Volume 9, Issue 5, Pages 4470-4476Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b00209
Keywords
visible-light catalysis; asymmetric catalysis; photochemistry; asymmetric cross coupling; fluorine
Categories
Funding
- NSFC [21432003]
- Fundamental Research Funds for the Central Universities
Ask authors/readers for more resources
In the past decades, the Cu-catalyzed asymmetric organic reactions have been well-developed. By contrast, the potential of Cu to serve as a chiral photocatalyst remains underexplored. We here report the visible-light-induced, Cu-catalyzed photoredox enantioselective cyanofluoroalkylation of alkenes. In the reaction, the Cu-based single catalyst played a dual role, as both the photoredox catalyst for the outer-sphere electron transfer and the asymmetric cross-coupling catalyst for enantioselective C-CN bond formation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available