Journal
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Volume 74, Issue 5, Pages 409-414Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/znb-2018-0270
Keywords
amide; crystal structure; magnetism; manganese(II)
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Funding
- Natural Science Foundation for Universities in Jiangsu Province [16KJB150005]
- Huaiyin Institute of Technology [15HGZ006, 491713325]
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A new Mn(II) complex [Mn-2(L)(H2O)(3)] center dot (H2O)(4.8) (1) was synthesized via the hydrothermal reaction of MnCl2 center dot 4H(2)O with N4, N4'-di(5-isophthalyl) biphenyl-4,4'- dicarboxamide (H4L). Complex 1 is characterized by single-crystal and powder X-ray diffraction, infrared spectroscopy, and elemental and thermogravimetric analyses. 1 exhibits a uninodal 5-connected 3D bnn framework structure with (4(6).6(4)) topology. The magnetic properties of 1 were investigated.
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