Journal
SYNTHESIS-STUTTGART
Volume 51, Issue 10, Pages 2081-2099Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1612420
Keywords
hemicryptophanes; chiral recognition; resolution; cyclotriveratrylene; supramolecular chemistry
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Funding
- Agence National de la Recherche (ANR, France, OH Risque grant) [ANR-14-OHRI-0015-03]
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Hemicryptophanes have recently emerged as an attractive class of cages due to their interesting applications as supramolecular receptors and catalysts. Over the last decade, substantial advances have been made regarding the preparation of enantiopure versions of these synthetic receptors. Enantiopure hemicryptophanes are commonly obtained through the separation of diastereomers by chromatography, or by resolution of racemic mixtures using chiral HPLC. This short review summarizes the existing methods to access to these chiral organic architectures and discusses the benefits and drawbacks of each approach.
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