Journal
SYNLETT
Volume 30, Issue 10, Pages 1199-1203Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1689934
Keywords
electrochemistry; electrocatalysis; anodically coupled electrolysis; alkene difunctionalization; radical addition; chlorination; phosphine oxide
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Funding
- Cornell University (Division of Chemistry)
- National Science Foundation (NSF) [CHE-1751839]
- National Science Foundation [CHE-1531632]
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We report the development of an electrocatalytic protocol for the chlorophosphinoylation of simple alkenes. Driven by electricity and mediated by a Mn catalyst, the heterodifunctionalization reaction takes place with high efficiency and regioselectivity. Cyclic voltammetry data are consistent with a mechanistic scenario based on anodically coupled electrolysis in which the generation of two distinct radical intermediates occur simultaneously on the anode and are both mediated by the Mn catalyst.
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