4.4 Article

1,10-Phenanthroline- or Electron-Promoted Cyanation of Aryl Iodides

Journal

SYNLETT
Volume 30, Issue 10, Pages 1209-1214

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1611793

Keywords

cyanation; organocatalysis; electrochemistry; aryl iodides; aryl cyanides

Funding

  1. JSPS [JP16K05695, JP16K05777, JP16H01155, JP18H04415]

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A 1,10-phenanthroline-promoted cyanation of aryl iodides has been developed. 1,10-Phenanthroline worked as an organocatalyst for the reaction of aryl iodides with tetraalkylammonium cyanide to afford aryl cyanides. A similar reaction occurred through an electroreductive process.

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