4.7 Article

Highly selective Fe3+ and F-/H2PO4- sensor based on a water-soluble cationic pillar[5]arene with aggregation-induced emission characteristic

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2019.117215

Keywords

Chemosensor; AIEgens; Self-assembly; Ion detection; Portable test kit; Encryption and decryption materials

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Funding

  1. National Natural Science Foundation of China [21661028, 21662031, 21574104]
  2. Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China [IRT 15R56]

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A water-soluble cationic pillar[5]arene (CWP5) without lager conjugated construction was first reported as a novel pillar[5]arene-based aggregation-induced emission luminogen (AIEgen), which showed a remarkable aggregation-induced emission (AIE) with the concentration increasing. The AIE effect of CWP5 has affected by different solvent, it had the lowest critical aggregation concentration (CAC) value and highest fluoresence emission intensity in DMSO solution. Simultaneously, CWP5 can serve as a chemosensor for the successively fluorescent detection of Fe3+ and F-/H2PO4- with high sensitivity and selectivity. A rewritable portable test kit made from CWP5 provides a possibility to on-site detection and manufacture of encryption and decryption materials. (C) 2019 Elsevier B.V. All rights reserved.

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