4.7 Article

A highly susceptive mesoporous hematite microcube architecture for sustainable P-type formaldehyde gas sensors

Journal

SENSORS AND ACTUATORS B-CHEMICAL
Volume 287, Issue -, Pages 437-444

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2019.01.153

Keywords

Mesoporous hematite microcube; P-type formaldehyde detection; Sub-ppm detection; Gas sensor

Funding

  1. Korea Institute of Energy Research [B92442-02]
  2. National Research Foundation of Korea [NRF-2017M3A9F1033056]

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The mesoporous hematite cubic frameworks (alpha-Fe2O3 microcube) with 2-3 mu m sizes were prepared using a simple thermal treatment of the iron oxalate hydrate cubes (4 mu m). The alpha-Fe2O3 microcube structure with a high surface area (36 m(2) g(-1)) had three-dimensionally connected small grain sizes ((similar to)18 nm). In formaldehyde (HCHO) gas sensing, the fabricated device by alpha-Fe2O3 microcubes shows excellent detection ability even at low HCHO concentration ((similar to)50 ppb) and high response reaching to R-gas/R-air = 5.2 at 1 ppm as well as long-term stability, compared with conventional Fe2O3 nanoparticles.

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