Journal
ANNUAL REVIEW OF ANALYTICAL CHEMISTRY, VOL 9
Volume 9, Issue -, Pages 365-+Publisher
ANNUAL REVIEWS
DOI: 10.1146/annurev-anchem-071015-041750
Keywords
coupled physical and chemical dynamics model; MALDI; ionization mechanisms; exciton pooling; ion-molecule reactions
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The coupled physical and chemical dynamics model of ultraviolet matrix-assisted laser desorption/ionization (MALDI) has reproduced and explained a wide variety of MALDI phenomena. The rationale behind and elements of the model are reviewed, including the photophysics, kinetics, and thermodynamics of primary and secondary reaction steps. Experimental results are compared with model predictions to illustrate the foundations of the model, coupling of ablation and ionization, differences between and commonalities of matrices, secondary charge transfer reactions, ionization in both polarities, fluence and concentration dependencies, and suppression and enhancement effects.
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