4.5 Article

An eco-friendly method for the preparation of poly(N-vinyl-2-pyrrolidone)-poly(vinyl alcohol) blend nanocomposite films containing vitamin B1-modified silica nanoparticles to enhance thermal and wettability properties

Journal

POLYMER BULLETIN
Volume 77, Issue 3, Pages 1489-1502

Publisher

SPRINGER
DOI: 10.1007/s00289-019-02814-y

Keywords

Surface modification; Vitamin B-1; PVP-PVA blend; Ultrasonic irradiation; Thermal resistance

Funding

  1. Research Affairs Division Isfahan University of Technology, Isfahan, I. R. Iran

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Incorporation of silica (SiO2) nanoparticles (NP)s within the poly(N-vinyl pyrrolidone)-poly(vinyl alcohol) (PVP-PVA) blend can improve its characteristics. Initially, the bio-compatible vitamin B-1 (VB1) was used for tailoring the surface of NPs and preventing them from aggregation. After that, the nanocomposite (NC) films of PVP-PVA combined with equal proportions were prepared by inserting various amounts of the modified SiO2 (SiO2-VB1). Uniform dispersal of the SiO2-VB1 inside the polymer was verified by means of microscopic observations. Optical as well as thermal characteristics revealed improvement after addition of the SiO2-VB1. Also, the NC with higher SiO2-VB1 content showed lower contact angle. This proposes the role of SiO2-VB1 NPs as a suitable filler to increase the wettability of the PVP-PVA blend.

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