Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 194, Issue 7, Pages 624-629Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2019.1602773
Keywords
Rare earth; monothioBINOL; hydrogen bonding; anionic
Categories
Funding
- National Science [CHE-1464744, CHE-1664928]
Ask authors/readers for more resources
Two novel rare earth compounds have been synthesized using the previously reported (S)-MonoThioBINOL [(S)-H-2-MTB], (S)-2-hydroxy-2 '-mercapto-1,1 '-binaphthyl). We have shown here that while the H-bonded complex containing TMG-H+ (tetramethyl guanidium cation) maintains the structure that the analogous BINOLate complex adopts, the complex with lithium cations in the secondary coordination sphere crystallizes as an '-ate' complex with an outer sphere lithium counter cation solvated by DME.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available